The
enthalpy of neutralization (
ΔHno) is the change in
enthalpy that occurs when an
acid and
base undergo a
neutralization reaction to form
water and a
salt. It is a special case of the
enthalpy of reaction.
When a reaction is carried out under
standard conditions at the temperature of 298 K and 1
atm of pressure, it is called the
standard enthalpy of neutralization.
The heat (
Q) released during a reaction is
- Q = m c ΔT
where
m is the mass of the solution,
c is the
specific heat capacity of the solution, and ∆
T is the temperature change observed during the reaction. From this, the standard enthalpy change (∆H) is obtained by division with the amount of substance (in
moles) involved, usually the amount of H
+ ions:
- ∆H = - Q/n
The standard enthalpy change of neutralization for a strong acid and base is -57.3 kJ/mol.
The standard enthalpy of neutralization for mineral acids is far greater than that of organic acids, because strong acids ionize completely while organic acids are usually weak and ionize only partially.
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